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Nicolas Leonard Sadi Carnot

Nicolas Leonard Sadi Carnot was a French military scientist and physicist, often described as the "father of thermodynamics". Like Copernicus, he published only one book, the Reflections on the Motive Power of Fire (Paris, 1824), in which he expressed, at the age of 27 years, the first successful theory of the maximum efficiency of heat engines. In this work he laid the foundations of an entirely new discipline, thermodynamics. Carnot's work attracted little attention during his lifetime, but it was later used by Rudolf Clausius and Lord Kelvin to formalize the second law of thermodynamics and define the concept of entropy.

Nicolas Leonard Sadi Carnot was born in Paris into a family that was distinguished in both science and politics. He was the first son of Lazare Carnot, an eminent mathematician, military engineer and leader of the French Revolutionary Army. Lazare chose his son's third given name (by which he would always be known) after the Persian poet Sadi of Shiraz. Sadi was the elder brother of statesman Hippolyte Carnot and the uncle of Marie Francois Sadi Carnot, who would serve as President of France from 1887 to 1894.

At the age of 16, Sadi Carnot became a cadet in the Ecole Polytechnique in Paris, where his classmates included Michel Chasles and Gaspard-Gustave Coriolis. The Ecole Polytechnique was intended to train engineers for military service, but its professors included such eminent scientists as Andre-Marie Ampere, Francois Arago, Joseph Louis Gay-Lussac, Louis Jacques Thenard and Simeon Denis Poisson, and the school had become renowned for its mathematical instruction. After graduating in 1814, Sadi became an officer in the French army's corps of engineers. His father Lazare had served as Napoleon's minister of the interior during the "Hundred Days", and after Napoleon's final defeat in 1815 Lazare was forced into exile. Sadi's position in the army, under the restored Bourbon monarchy of Louis XVIII, became increasingly difficult.

In 1819, Sadi transferred to the newly formed General Staff, in Paris. He remained on call for military duty, but from then on he dedicated most of his attention to private intellectual pursuits and received only two-thirds pay. Carnot befriended the scientist Nicolas Clement and attended lectures on physics and chemistry. He became interested in understanding the limitation to improving the performance of steam engines, which led him to the investigations that became his Reflections on the Motive Power of Fire, published in 1824.

When Carnot began working on his book, steam engines had achieved widely recognized economic and industrial importance, but there had been no real scientific study of them. Newcomen had invented the first piston-operated steam engine over a century before, in 1712; some 50 years after that, James Watt made his celebrated improvements, which were responsible for greatly increasing the efficiency and practicality of steam engines. Compound engines (engines with more than one stage of expansion) had already been invented, and there was even a crude form of internal-combustion engine, with which Carnot was familiar and which he described in some detail in his book. Although there existed some intuitive understanding of the workings of engines, scientific theory for their operation was almost nonexistent. In 1824 the principle of conservation of energy was still poorly developed and controversial, and an exact formulation of the first law of thermodynamics was still more than a decade away; the mechanical equivalence of heat would not be formulated for another two decades. The prevalent theory of heat was the caloric theory, which regarded heat as a sort of weightless and invisible fluid that flowed when out of equilibrium.

Perhaps the most important contribution Carnot made to thermodynamics was his abstraction of the essential features of the steam engine, as they were known in his day, into a more general and idealized heat engine. This resulted in a model thermodynamic system upon which exact calculations could be made, and avoided the complications introduced by many of the crude features of the contemporary steam engine. By idealizing the engine, he could arrive at clear and indisputable answers to his original two questions.

The Carnot cycle is the most efficient possible engine, not only because of the (trivial) absence of friction and other incidental wasteful processes; the main reason is that it assumes no conduction of heat between parts of the engine at different temperatures. Carnot knew that the conduction of heat between bodies at different temperatures is a wasteful and irreversible process, which must be eliminated if the heat engine is to achieve maximum efficiency.

Carnot died during a cholera epidemic in 1832, at the age of 36. (Asimov 1982, p. 332) Because of the contagious nature of cholera, many of Carnot's belongings and writings were buried together with him after his death. As a consequence, only a handful of his scientific writings survived.

Carnot published his book in the heyday of steam engines. His theory explained why steam engines using superheated steam were better because of the higher temperature of the consequent hot reservoir. Carnot's theories and efforts did not immediately help improve the efficiency of steam engines; his theories only helped to explain why one existing practice was superior to others. It was only towards the end of the nineteenth century that Carnot's ideas, namely that a heat engine can be made more efficient if the temperature of its hot reservoir is increased, were put into practice. Carnot's book did, however, eventually have a real impact on the design of practical engines. Rudolf Diesel, for example, used Carnot's theories to design the diesel engine, in which the temperature of the hot reservoir is much higher than that of a steam engine, resulting in an engine which is more efficient.